Details
Factory Sells Best Quality LUTETIUM FLUORIDE 13760-81-1 with USP
- Molecular Formula: LuF3
- Molecular Weight: 231.962
- Appearance/Colour: white fine crystalline powder
- Melting Point: 1182 °C
- Boiling Point: 2200oC
- PSA: 0.00000
- Density: 8.332
- LogP: 1.26060
LUTETIUM FLUORIDE(Cas 13760-81-1) Usage
InChI:InChI=1/3FH.Lu/h3*1H;/q;;;+3/p-3
13760-81-1 Relevant articles
Experimental study of the enthalpy of lutetium trifluoride in solid and liquid states
Lyapunov,Baginskii,Stankus
, p. 7 - 9 (2004)
The high temperature enthalpy of high pu...
Infrared spectra and quantum chemical calculations of the bridge-bonded HC(F)LnF2 (Ln = La-Lu) complexes
Gong, Yu,Wang, Xuefeng,Andrews, Lester,Chen, Mingyang,Dixon, David A.
, p. 4443 - 4452 (2011/10/10)
Lanthanide metal atoms, produced by lase...
Optically active uniform potassium and lithium rare earth fluoride nanocrystals derived from metal trifluroacetate precursors
Du, Ya-Ping,Zhang, Ya-Wen,Sun, Ling-Dong,Yan, Chun-Hua
, p. 8574 - 8581 (2011/01/06)
This paper reports the first systematica...
Thermochemical studies on the lanthanoid complexes of trifluoroacetic acid
Yoshimura,Ohara
, p. 573 - 576 (2008/10/09)
The thermal decomposition of the lanthan...
13760-81-1 Process route
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lutetium(III) oxide
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7664-39-3,12381-92-9,32057-09-3,74835-82-8
hydrogen fluoride
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13760-81-1
lutetium(III) fluoride
| Conditions | Yield |
|---|---|
|
In
neat (no solvent);
byproducts: H2O; at elevated temp.;;
|
|
|
In
neat (no solvent);
byproducts: H2O; formation of hydrated compound with moist HF at 150-250°C, dehydration at 350-550.degreee.C with dry HF containing 10% H2;;
|
|
|
In
neat (no solvent);
byproducts: H2O; on passing dry HF-gas over oxide at 700°C, 200% excess HF, cooling to room temp. under diminished pressure, removal of HF by passing through He;;
|
99.90-99.98
|
|
In
hydrogenchloride; nitric acid;
Lu2O3 was dissolved in HCl-HNO3, pptd. with HF, dehydrated under streamof HF-N2 at temp. gradually raised to about 1000 K;
|
|
|
In
hydrogenchloride;
addn. of HF to soln. of Lu2O3, pptn., drying (air, 390 K), dehydration (stream of HF/N2, 1000 K); distn. (vac., 1570 K);
|
|
|
In
gaseous matrix;
heating (platinum boat, dynamic HF/Ar atmosphere, at 1023 K for 16 h and at 50 K above melting temp. for 8 h); elem. anal.;
|
|
|
In
hydrogenchloride;
pptn., drying in air (390 K), heating under HF/N2 stream (1000 K); distn. (high vac.);
|
|
|
In
not given;
(HF); hydrofluorination at high temp.;
|
-
-
ammonium fluoride
-
-
lutetium(III) oxide
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13760-81-1
lutetium(III) fluoride
| Conditions | Yield |
|---|---|
|
In
neat (no solvent);
excess fluoride, 200°C, Pt-vessel; removal of excess fluoride on heating in a stream of dry inert gas to 450°C;;
|
|
|
In
hydrogenchloride;
dissolving oxide in aq. HCl, pptn. with excess aq. NH4F, filtration, drying, dehydration on heating ppt. with excess powdered NH4F to 360°C in a dry stream of He or Ne (O2-free) for 5h;;
|
|
|
In
hydrogenchloride;
dissolving oxide in aq. HCl, pptn. with excess aq. NH4F, filtration, drying, dehydration on heating ppt. with excess powdered NH4F to 360°C in a dry stream of He or Ne (O2-free) for 5h;;
|
|
|
With
HF;
In
hydrogen fluoride;
aq. HF; lanthanide trifluoride is treated with 40% hydrofluoric acid with stirring, decanting the HF, drying under an infrared heater at 50°C, mixing with NH4F, heating at 500°C; XRD, DTA;
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13760-81-1 Upstream products
-
13709-36-9
xenon difluoride
-
7790-91-2
chlorine trifluoride
-
7664-39-3
hydrogen fluoride
-
7790-79-6
cadmium(II) fluoride
13760-81-1 Downstream products
-
13598-44-2
lutetium
-
36781-15-4
terbium tetrafluoride
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